Which reactant, and how many grams of it, is left over after 16.0 g of MnO2 (FW = 86.9 g/mol) and 30.0 g of HCl (FW = 36.5 g/mol) react according to the following chemical equation?MnO2 + 4 HCl ® MnCl2 + Cl2 + 2 H2O3.1 g HCl23.3 g HCl4.02 g MnO28.0 g MnO212.1 g MnO2

Respuesta :

Answer : The HCl reactant is left over in the reaction and the left over amount of HCl is, 3.1 grams

Explanation : Given,

Mass of [tex]MnO_2[/tex] = 16.0 g

Mass of [tex]HCl[/tex] = 30.0 g

Molar mass of [tex]MnO_2[/tex] = 87 g/mole

Molar mass of [tex]HCl[/tex] = 36.5 g/mole

First we have to calculate the moles of [tex]MnO_2[/tex] and [tex]HCl[/tex].

[tex]\text{Moles of }MnO_2=\frac{\text{Mass of }MnO_2}{\text{Molar mass of }MnO_2}=\frac{16g}{87g/mole}=0.184moles[/tex]

[tex]\text{Moles of }HCl=\frac{\text{Mass of }HCl}{\text{Molar mass of }HCl}=\frac{30g}{36.5g/mole}=0.822moles[/tex]

Now we have to calculate the limiting and excess reagent.

The balanced chemical reaction is,

[tex]MnO_2+4HCl\rightarrow MnCl_2+Cl_2[/tex]

From the balanced reaction we conclude that

As, 1 moles of [tex]MnO_2[/tex] react with 4 mole of [tex]HCl[/tex]

So, 0.184 moles of [tex]MnO_2[/tex] react with [tex]4\times 0.184=0.736[/tex] moles of [tex]HCl[/tex]

From this we conclude that, [tex]HCl[/tex] is an excess reagent because the given moles are greater than the required moles and [tex]MnO_2[/tex] is a limiting reagent and it limits the formation of product.

The excess moles of HCl = 0.822 - 0.736 = 0.086 mole

Now we have to calculate the mass of [tex]HCl[/tex].

[tex]\text{Mass of }HCl=\text{Moles of }HCl\times \text{Molar mass of }HCl[/tex]

[tex]\text{Mass of }HCl=(0.086mole)\times (36.5g/mole)=3.139g\approx 3.1g[/tex]

Therefore, the HCl reactant is left over in the reaction and the left over amount of HCl is, 3.1 grams