Consider benzene in the gas phase, C6H6(g)Use the heat of formation, ΔH∘f , values below to answer the questions.

Substance H(g) C(g) C6H6(g) ΔH∘f (kJ/mol ) 217.94 718.4 82.9

Part A


What is the standard enthalpy change for the reaction that represents breaking all the bonds in gaseous benzene, C6H6(g) ?


Express your answer to one decimal place and include the appropriate units.


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Part B


What is the chemical equation for the reaction that corresponds to breaking just the carbon-carbon bonds in gaseous benzene, C6H6(g) ? Indicate the phase of each species in your answer.


Express your answer as a chemical equation including phases.

Respuesta :

Answer: 5535.1KJ/mol

Explanation:The equation for breaking of all the bonds in the benzene is written as follows:

C_6 H_6(g) --> 6C(g) +6H (g)

∆H_rxn= ∑moles of product X∆H_PRODUCT -∑moles of reactants x ∆H_REACTANT  

={6mols X ∆H_°f(C) + 6mols X ∆H_°f(H)} –{1 mol ∆H_°fC_6 H_6 (g)

={6 X 217.74+ 6X 718.4} – {82.9}KJ/mol

= 5618.04 – 82.9 KK/mol

=5535.1KJ/mol

b) The equation for the breaking of the carbon-carbon bonds in benzene is illustrated below as

C_6 H_6(g) --> 6C---H (g)

A) The standard enthalpy change for the reaction is ; 5535.1 KJ/mol

B) The chemical equation for the reaction that corresponds to breaking just the carbon-carbon bonds is  :  C₆H₆(g) --> 6C---H(g)

A) The standard enthalpy change for the reaction which represents breaking of all bonds

Reaction equation ; C₆H₆(g) --> 6C(g) +  6H (g)

∆H = ∑ ( moles of product * ∆Hpro ) - ( moles of reactant * ∆H reactant )

      = ( 6 * 217.94  +  6 *  718.4 ) –  ( 82.9)   KJ/mol

      = ( 5618.04 ) - ( 82.9 ) = 5535.1  KJ/mol

B) The chemical equation for the reaction that corresponds to breaking the carbon-carbon bonds

chemical equation  = C₆H₆(g) --> 6C---H(g)

Hence we can conclude that The answers to your questions are 5535.1 KJ/mol and C₆H₆(g) --> 6C---H(g)

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